Initially such a strange old name for a cathedral city (5)
I believe the answer is:
sarum
'old name for a cathedral city' is the definition.
I can't tell whether this definition defines the answer.
'initially such a strange' is the wordplay.
'initially' suggests taking the first letters.
'strange' becomes 'rum' (synonyms).
The first letter of 'such' is 's'.
's'+'a'+'rum'='SARUM'
Can you help me to learn more?
(Other definitions for sarum that I've seen before include "Wiltshire diocese" , "Ancient name of Salisbury" .)