Instruction book? (5)
I believe the answer is:
order
I believe this clue is a double definition.
'instruction' is the first definition.
(an order to do something)
'book?' is the second definition.
(order book is a kind of book)
(Other definitions for order that I've seen before include "Arrange < company" , "Arrangement; command" , "Command or request for goods" , "Kind - sort" , "Apply for - class" .)