Instructor leaves chapter? Not appropriate! (7)
I believe the answer is:
teacher
'instructor' is the definition.
(synonyms)
'leaves chapter? not appropriate' is the wordplay.
'leaves' becomes 'tea' (as in tea leaves).
'chapter?' becomes 'ch'.
'not appropriate' becomes 'er' (I can't explain this - if you can you should give a lot more credence to this answer).
'tea'+'ch'+'er'='TEACHER'
Can you help me to learn more?
(Other definitions for teacher that I've seen before include "supply?" , "Pedagogue" , "Mentor" , "Schoolmaster/mistress" , "Guide" .)