Instrument is deflecting pitch (5)
I believe the answer is:
sitar
'instrument' is the definition.
(sitar is a type of musical instrument)
'deflecting pitch' is the wordplay.
'deflecting' becomes 'si' (I am not sure about this - if you are sure you should give a lot more credence to this answer).
'pitch' becomes 'tar' (synonyms).
'si'+'tar'='SITAR'
'is' acts as a link.
Can you help me to learn more?
(Other definitions for sitar that I've seen before include "Guitar-like instrument" , "Indian string instrument" , "instrument out east" , "Indian stringed instrument" , "Hindu stringed instrument" .)