Intense and very very angry, blowing top (5)
I believe the answer is:
vivid
'intense' is the definition.
(synonyms)
'very very angry blowing top' is the wordplay.
'very' becomes 'v' (abbreviation).
'very angry' becomes 'livid' (I've seen this before).
'blowing top' means to remove the first letter.
'livid' with its first letter removed is 'ivid'.
'v'+'ivid'='VIVID'
'and' acts as a link.
(Other definitions for vivid that I've seen before include "Presenting a clear and striking picture" , "Brightly coloured" , "Strong and bright, colour perhaps" , "Fresh and bright" , "Lifelike, striking" .)