Internally typecasting cranky, unlovable amorous adventurer (8)
I believe the answer is:
casanova
'amorous adventurer' is the definition.
(I've seen this before)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for casanova that I've seen before include "Notorious lover" , "Notorious Italian womaniser of 18th century" , "Man noted for his amorous adventures" , "Lady-killer" , "Famous Italian" .)