Intimate devil embraces Russians' leader (6)
I believe the answer is:
friend
'intimate' is the definition.
(intimate can mean a friend)
'devil embraces russians' leader' is the wordplay.
'devil' becomes 'fiend' (synonyms).
'embraces' is an insertion indicator.
'russians' leader' becomes 'r' (I can't explain this - if you can you should give a lot more credence to this answer).
'fiend' enclosing 'r' is 'FRIEND'.
Can you help me to learn more?
(Other definitions for friend that I've seen before include "Ally, supporter" , "allowed to pass by the guard" , "Companion; Quaker" , "Person regarded with trust and affection" , "One who gives proof of genuine regard" .)