Islander's copper prohibition (5)
I believe the answer is:
cuban
'islander's' is the definition.
(I've seen this before)
'copper prohibition' is the wordplay.
'copper' becomes 'cu' (chemical symbol).
'prohibition' becomes 'ban' (synonyms).
'cu'+'ban'='CUBAN'
(Other definitions for cuban that I've seen before include "Like Fidel Castro" , "Citizen of Castro's country" , "Kind of high quality cigar" , "Havana native" , "Republican" .)