It may well offer light relief (6)
I believe the answer is:
window
'light relief' is the definition.
'window' can be an answer for 'light' (light can mean a window or opening). I'm not sure about the 'relief' bit.
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for window that I've seen before include "Glazed opening" , "Shop display area" , "Eg, oriel or fanlight" , "Opening to admit light" , "See 1 down" .)