Italian region, capital Florence (7)
I believe the answer is:
tuscany
I believe this clue is a double definition.
'italian region' is the first definition.
(Tuscany is an example)
'capital florence' is the second definition.
(I know that Tuscany capital Florence)
(Other definitions for tuscany that I've seen before include "'Chiantishire'" , "N. Italian region" , "Region of Central Italy, chief city Florence." , "somewhere in Italy" , "part of Italy" .)