Item well-heeled philatelists could bid for when Sotheby's auctioned it for a seven figure sum in 2024 (5,5)
I believe the answer is:
penny black
(Other definitions for penny black that I've seen before include "when without means to send a letter" , "Today one would be unlikely to lick this" , "World's first adhesive postage stamp, 1840" , "first to get licked" .)