It's brilliant being the chap in charge! (5)
I believe the answer is:
super
'it's brilliant' is the definition.
(I've seen this before)
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for super that I've seen before include "Fantastic" , "Topnotch, terrific" , "Prefix meaning over-excellent!" , "Gushily great, excellent" , "senior cop" .)