It's not safe to start riding on something high (5)
I believe the answer is:
risky
'high' is the definition.
Both the definition and answer are adjectives. Perhaps there's an association between them I don't understand?
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for risky that I've seen before include "Hazardous" , "Treacherous" , "taking a chance" , "admitting possibility of unpleasant outcome" , "Potentially dangerous" .)