It's overwhelming snatching a bit of fresh air? (12)
I believe the answer is:
breathtaking
'it's overwhelming' is the definition.
(thesaurus)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for breathtaking that I've seen before include "Awe-inspiring" , "way of getting air into the lungs" , "Awesome" , "Astounding" , "if one is not one is dead?" .)