It's useful when bending the elbow (6)
I believe the answer is:
biceps
'elbow' is the definition.
(thesaurus)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for biceps that I've seen before include "Muscle that flexes the forearm" , "Arm muscles" , "Weightlifters use them" , "Arm workers" , "Elbow-bending muscle" .)