It's very hard but laundrymaids do it (4)
I believe the answer is:
iron
'it' is the definition.
The definition suggests a singular noun which matches the answer.
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for iron that I've seen before include "rations in emergency?" , "sort of club" , "Very robust" , "Heavy metallic element" , "Club; element" .)