Jack, boy in waterproof stuff (9)
I believe the answer is:
tarpaulin
'waterproof stuff' is the definition.
(waterproof material)
'jack boy in' is the wordplay.
'jack' becomes 'tar' (both are informal terms for sailor).
'boy' becomes 'Paul' (boy's name).
'tar'+'paul'+'in'='TARPAULIN'
(Other definitions for tarpaulin that I've seen before include "Waterproofed canvas" , "waterproof material" , "sailor's hat" , "oilskin hat" , "protective cover" .)