Jack has to sing out, looking amazed (3)
I believe the answer is:
tar
'jack' is the definition.
(both are informal terms for sailor)
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for tar that I've seen before include "Thick flammable liquid" , "Black coat" , "Cigarette residue - old word for sailor" , "Jack ..., British sailor" , "Product of coal" .)