Jacket, not a twinset (7)
I believe the answer is:
doublet
'jacket' is the definition.
(doublet is a kind of jacket)
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for doublet that I've seen before include "Formerly, a man's close-fitting jacket" , "Close-fitting jacket (14th to 17th century)" , "Old garment worn with hose" , "Historical jacket" , "Close-fitting padded jacket of Tudor and Stuart England" .)