Jack's a rogue! (5)
I believe the answer is:
knave
This clue is a double definition.
'jack's' is the first definition.
('knave' can be a synonym of 'jack')
'a rogue' is the second definition.
('knave' can be a synonym of 'rogue')
(Other definitions for knave that I've seen before include "Jack - scoundrel" , "one found amongst thieves" , "Rapscallion" , "Yet he may be a diamond" , "[COURT CARD] , maybe" .)