Join a silent assembly (6)
I believe the answer is:
enlist
'join' is the definition.
(I know that enlist is a type of sign up)
'a silent assembly' is the wordplay.
'assembly' indicates an anagram.
'silent' anagrammed gives 'ENLIST'.
(Other definitions for enlist that I've seen before include "Engage" , "Join up in silent way" , "Join the armed services" , "Join the army" , "Enrol in the services" .)