Joint leader in church may let it go to his head (5)
I believe the answer is:
mitre
'joint' is the definition.
(I know that mitre is a type of joint)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for mitre that I've seen before include "Merit (anag.)" , "in which one might find a bishop" , "Bishop's cap - wood joint" , "Corner joint - bishop's hat" , "bishop's head?" .)