Knocks back Pedro Ximenez in Irish river bar (5)
I believe the answer is:
expel
'bar' is the definition.
(thesaurus)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for expel that I've seen before include "Drive out, banish" , "Eject (from school)" , "Discharge in disgrace" , "Get rid" , "Reject" .)