Knowing just what you have in mind (10)
I believe the answer is:
telepathic
'knowing' is the definition.
Both the answer and definition are adjectives. Perhaps you can see a link between them that I can't see?
I don't understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for telepathic that I've seen before include "Able to pick up ideas" , "Extraordinarily communicative" , "Clairvoyant" , "Mind-reading" , "Communicating by mind alone" .)