Leaders make stars align (5)
I believe the answer is:
tsars
'leaders' is the definition.
'stars align' is the wordplay.
'stars' can be anagrammed to 'TSARS'.
Though, I am not sure how this is indicated.
'make' is the link.
Can you help me to learn more?
(Other definitions for tsars that I've seen before include "Old Russia's rulers" , "Old monarchs" , "Old Russian rulers" , "Russian emperors" .)