Let money relieve matters (5)
I believe the answer is:
lease
'let' is the definition.
('lease' can be a synonym of 'let')
'money relieve matters' is the wordplay.
'money' becomes 'l' (L can mean 'pounds').
'relieve matters' becomes 'ease' (I can't justify this - if you can you should believe this answer much more).
'l'+'ease'='LEASE'
Can you help me to learn more?
(Other definitions for lease that I've seen before include "Letting contract" , "Contract of tenure" , "Let for money" , "Property rental agreement" , "Renting contract" .)