Lighting up time! (5)
I believe the answer is:
night
'time' is the definition.
(I know that night is a type of crepuscle)
I cannot understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for night that I've seen before include "A Hard Day's (the Beatles)" , "See 1 Across" , "Saturday -- Fever (film)" , "That's when it's darkest" , "follow-up to 16 [TWILIGHT]" .)