Litigation is a troublesome thing (5)
I believe the answer is:
trial
'litigation' is the definition.
(thesaurus)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for trial that I've seen before include "Court hearing" , "Legal hearing" , "French actor who sings" , "Testing, experiment" , "Court appearance on charge - it's an ordeal" .)