Long way to go for a hat! (6)
I believe the answer is:
panama
'hat' is the definition.
(panama is a kind of hat)
'long way to go for a' is the wordplay.
'long way to go' becomes 'panam' (I can't justify this - if you can you should give a lot more credence to this answer).
'for' is a charade indicator (letters next to each other).
'panam'+'a'='PANAMA'
Can you help me to learn more?
(Other definitions for panama that I've seen before include "Land - hat - cigar" , "Canal state; hat" , "Headgear for a canal" , "'Country, canal and hat (6)'" , "Central American country" .)