Longed to join soldiers on top, got there (5)
I believe the answer is:
ached
'longed' is the definition.
('ache' can be a synonym of 'long')
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for ached that I've seen before include "Throbbed" , "suffered" , "Felt a dull pain" , "Did long" , "Yearned" .)