Manual detonator (6)
I believe the answer is:
primer
This clue is a double definition.
'manual' is the first definition.
(thesaurus)
'detonator' is the second definition.
(thesaurus)
(Other definitions for primer that I've seen before include "device for detonating charge" , "Initial coat of paint" , "instructive book" , "Elementary textbook" , "Preparatory coat of paint" .)