Manxman, for example, doesn't start defamation (7)

I believe the answer is:
slander
'defamation' is the definition.
(I know that defamation can be written as slander)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for slander that I've seen before include "Sling mud at" , "False/malicious speech" , "muckraking!" , "Malicious speech" , "Calumny" .)