Mark put on female item of clothing (5)
I believe the answer is:
scarf
'item of clothing' is the definition.
(I've seen this before)
'mark put on female' is the wordplay.
'mark' becomes 'scar' (synonyms).
'put on' is a charade indicator (letters next to each other).
'female' becomes 'f' (common abbreviation).
'scar'+'f'='SCARF'
(Other definitions for scarf that I've seen before include "bit of football memorabilia?" , "Item worn on head or shoulders" , "Winter neckwear" , "Neckerchief - timber joint" , "May cover the neck" .)