Material doesn't start as a problem (5)
I believe the answer is:
issue
This clue could be a double definition.
'material doesn't start' is the first definition.
'issue' can be an answer for 'start' (thesaurus). I'm unsure of the 'material doesn't' bit.
'a problem' is the second definition.
(I've seen this in another clue)
'as' is the link.
Can you help me to learn more?
(Other definitions for issue that I've seen before include "Outcome - children" , "Offspring; problem" , "Number (of periodical)" , "Problem or concern" , "Sprogs" .)