Material for McDormand's first Oscar will grow on you (6)
I believe the answer is:
mohair
'material' is the definition.
(mohair is a kind of material)
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for mohair that I've seen before include "Fabric made from fine silky wool of goat" , "Fine silky wool of the angora goat" , "coat required" , "Fine silky coat of angora goat" , "Fabric made from Angora goat wool" .)