Material relating to the sides of the skull (8)
I believe the answer is:
temporal
'material' is the definition.
(thesaurus)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for temporal that I've seen before include "Nothing spiritual" , "about the side of the head" , "on the Head's side?" , "Of wordly affairs, not spiritual" , "Relating to time" .)