Material that's light when worn (5)
I believe the answer is:
rayon
'material' is the definition.
(rayon is a type of fabric)
'light when worn' is the wordplay.
'light when' becomes 'ray' (ray is a kind of light. I am not sure about the 'when' bit.).
'worn' becomes 'on' (as in having clothes on).
'ray'+'on'='RAYON'
'that's' is the link.
Can you help me to learn more?
(Other definitions for rayon that I've seen before include "Synthetic material" , "No ray (anag)" , "Or any (anag) -- fibre" , "Cellulose fabric" , "Artificial fibre" .)