Maybe three can put you to sleep (5)
I believe the answer is:
ether
'put you to sleep' is the definition.
I can't tell whether this definition defines the answer.
'maybe three' is the wordplay.
'maybe' indicates anagramming the letters.
'three' anagrammed gives 'ETHER'.
'can' acts as a link.
Can you help me to learn more?
(Other definitions for ether that I've seen before include "Old anaesthetic -- three (anag)" , "Medium supposedly" , "The gas is there, oddly" , "Liquid used as anaesthetic/ solvent" , "Anaesthetic; clear sky (poetic)" .)