Members of kingdom are amusing Joe (5)
I believe the answer is:
fungi
'members of kingdom' is the definition.
'Fungi' can be an answer for 'kingdom' (Fungi is an example). I am not certain of the 'members of' bit.
'amusing joe' is the wordplay.
'amusing' becomes 'fun' (synonyms).
'joe' becomes 'GI' (GI Joe).
'fun'+'gi'='FUNGI'
'are' is the link.
Can you help me to learn more?
(Other definitions for fungi that I've seen before include "rusts?" , "Mushrooms, toadstools etc (5)" , "life in woodland?" , "woodland feature" , "Spore producers" .)