Men she arranged to catch (6)
I believe the answer is:
enmesh
'catch' is the definition.
(thesaurus)
'men she arranged' is the wordplay.
'arranged' indicates an anagram.
'men'+'she'='menshe'
'menshe' with letters rearranged gives 'ENMESH'.
'to' acts as a link.
(Other definitions for enmesh that I've seen before include "Involve, as in a net" , "Entrap" , "snare" , "Catch in toils" , "Entangle as in net" .)