Metal van (4)
I believe the answer is:
lead
I believe this is a double definition.
'metal' is the first definition.
(lead is a kind of metal)
'van' is the second definition.
(van can mean the front of something)
(Other definitions for lead that I've seen before include "spearhead" , "Live" , "Go ahead; element" , "conductor of electricity" , "Heavy malleable metallic element" .)