Miss warning: "broadcast on air” (9)
I believe the answer is:
signorina
'miss' is the definition.
(I've seen this before)
'warning broadcast on air' is the wordplay.
'warning' becomes 'sign' (I've seen this in other clues).
'broadcast' is an anagram indicator (letters scattered or cast around).
'on'+'air'='onair'
'onair' anagrammed gives 'orina'.
'sign'+'orina'='SIGNORINA'
(Other definitions for signorina that I've seen before include "Foreign maid" , "Young lady from Rome?" , "Italian equivalent of "mademoiselle"" , "Girl from Parma, maybe" , "Italian girl revealed" .)