More explosive in capital (4)
I believe the answer is:
rome
'capital' is the definition.
(capital of Italy)
'more explosive' is the wordplay.
'explosive' is an anagram indicator.
'more' is an anagram of 'ROME'.
'in' acts as a link.
(Other definitions for rome that I've seen before include "Basis for cheese" , "All roads lead to it" , "Capital of Italy" , "The Eternal City" , "Colosseum city" .)