Crossword Genius

Most daring underwear for both sexes (7)

Ross

I believe the answer is:

bravest

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'most daring' is the definition.
(I've seen this before)

'underwear for both sexes' is the wordplay.
'underwear' becomes 'bra' (bra is a type of undergarment).
'for both sexes' becomes 'vest' (I am not sure about this - if you are sure you should give a lot more credence to this answer).
'bra'+'vest'='BRAVEST'

Can you help me to learn more?

(Other definitions for bravest that I've seen before include "Most courageous" , "Most valiant" , "Most daring" , "Most handsome" , "Most heroic" .)

I've seen this clue in The Telegraph.
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