Musketeer has a pitiable air, having lost hat (5)
I believe the answer is:
athos
'musketeer' is the definition.
(musketeer from The Three Musketeers)
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for athos that I've seen before include "Greek monastic mountain" , "Greece's holy mount" , "Comrade of Porthos and Aramis" , "Mount - musketeer" , "Brave soldier" .)