Natural love and caring, oddly (7)
I believe the answer is:
organic
'natural' is the definition.
('organic' can be similar in meaning to 'natural')
'love and caring oddly' is the wordplay.
'love' becomes 'o' (In tennis, 'love' means 'zero').
'and' means one lot of letters go next to another.
'oddly' is an anagram indicator.
'caring' with letters rearranged gives 'rganic'.
'o'+'rganic'='ORGANIC'
(Other definitions for organic that I've seen before include "Free of pesticides" , "Chemical and GM free" , "Formed from living things - no cigar for this one" , "structured" , "Non-chemical" .)