Next to Canada, it's the biggest thing of its kind (6)
I believe the answer is:
alaska
'kind' is the definition.
Although both the answer and definition are singular nouns, I don't see how one could define the other.
I cannot understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for alaska that I've seen before include "Sarah Palin's home state" , "49th US state" , "Most northerly state of America" , "Forty-ninth US state" , "Anchorage location" .)