Nice bloke's casual wear (5)
I believe the answer is:
jeans
'casual wear' is the definition.
I don't understand how the remainder of the clue works.
(Other definitions for jeans that I've seen before include "Trousers made of strong cotton, usually dyed blue" , "Denim trousers" , "(Usually) blue casual wear" , "article of clothing" , "Casual trousers, sometimes stonewashed?" .)