Nice lady cooked cakes in the morning (6)
I believe the answer is:
madame
'nice lady' is the definition.
(title for a woman in France eg in Nice)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for madame that I've seen before include "A French-speaking woman" , "Married woman in Montpellier?" , "Married woman abroad" , "Title for a Frenchwoman" , "Frenchwoman's title" .)