No mere mortal, I guess (6)
I believe the answer is:
divine
'guess' is the definition.
(divining is a kind of guessing)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for divine that I've seen before include "Apprehend" , "Of or coming from God" , "Find water" , "clergyman" , "Supreme" .)